[39] Synthetic Access to Benzimidacarbocyanine Dyes to Tailor Their Aggregation Properties.

bjheynegroup
May 22
1 min read

Roth, SM*; Press, DJ*; Heyne, B; Sutherland, TC. (2021). Synthetic Access to Benzimidacarbocyanine Dyes to Tailor Their Aggregation Properties. Journal of Organic Chemistry. 86(13): 8641–8651.

Developing structure–aggregation relationships of cyanine dyes is crucial for controlling their optical properties for various uses. This study develops a synthetic route and the structure-dependent self-assembly of a family of benzimidacarbocyanine dyes for J- or H-aggregation properties. It was found that both the presence and placement of halogen atoms play a defining role in the resulting supramolecular interactions of these compounds.

Comments

[54] Beyond Plasmonic Expectations: Micellar confinement governs the Norrish type I reaction in hybrid micelle-gold nanoparticle systems.

[53] Measuring molecular singlet oxygen (1O2*) from atmospheric photosensitizers: Intercomparison of techniques, irradiation setups, data analysis and protocol recommendations.

[52] Bioconjugates of Toluidine Blue Derivatives with Human Serum Albumin and Their Complexes with Cucurbit[7]uril as Drug Delivery Vehicles for Photodynamic Therapy

[51] Type I and Type II photosensitization of DNA etheno adducts.

[50] aPDI meets PPE: photochemical decontamination in healthcare using methylene blue—where are we now, where will we go?

[49] Supramolecular complex of tetracationic porphyrin with acyclic cucurbituril-like container induces quantitative singlet oxygen generation. Phototoxicity studies in vitro in MCF-7 human breast...

[48] Hydroaminoalkylation for Amine Functionalization of Vinyl-Terminated Polyethylene Enables Direct Access to Responsive Functional Materials.

[47] Extraordinary Control of Photosensitized Singlet Oxygen Generation by Acyclic Cucurbituril-like Containers.

[46] On the Molecular Origin of the Red Emission in the Newly Synthesized Carbon-based Quantum Dots.

[45] Of masks and methylene blue—The use of methylene blue photochemical treatment to decontaminate surgical masks contaminated with a tenacious small nonenveloped norovirus.

Heyne Group